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91.
The impacts of diurnal atmosphere–ocean (air–sea) coupling on tropical climate simulations are investigated using the SNU coupled GCM. To investigate the effect of the atmospheric and oceanic diurnal cycles on a climate simulation, a 1-day air–sea coupling interval experiment is compared to a 2-h coupling experiment. As previous studies have suggested, cold temperature biases over equatorial western Pacific regions are significantly reduced when diurnal air–sea coupling strategy is implemented. This warming is initiated by diurnal rectification and amplified further by the air–sea coupled feedbacks. In addition to its effect on the mean climatology, the diurnal coupling has also a distinctive impact on the amplitude of the El Nino-Southern Oscillation (ENSO). It is demonstrated that a weakening of the ENSO magnitude is caused by reduced (increased) surface net heat fluxes into the ocean during El Nino (La Nina) events. Primarily, decreased (increased) incoming shortwave radiation during El Nino (La Nina) due to cloud shading is responsible for the net heat fluxes associated with ENSO.  相似文献   
92.
The coexistence of magmatic anhydrite and sulfide minerals in non-arc-related mafic magmas has only rarely been documented. Likewise the S isotope fractionation between sulfate and sulfide in mafic rocks has infrequently been measured. In the Kharaelakh intrusion associated with the world-famous Noril’sk ore district in Siberia coexisting magmatic anhydrite and sulfide minerals have been identified. Sulfur isotope compositions of the anhydrite-sulfide assemblages have been measured via both ion microprobe and conventional analyses to help elucidate the origin of the anhydrite-sulfide pairs. Magmatic anhydrite and chalcopyrite are characterized by δ34S values between 18.8‰ and 22.8‰, and 9.3‰ and 13.2‰, respectfully. Coexisting anhydrite and chalcopyrite show Δ values that fall between 8.5‰ and 11.9‰. Anhydrite in the Kharaelakh intrusion is most readily explained by the assimilation of sulfate from country rocks; partial reduction to sulfide led to mixing between sulfate-derived sulfide and sulfide of mantle origin. The variable anhydrite and sulfide δ34S values are a function of differing degrees of sulfate reduction, variable mixing of sulfate-derived and mantle sulfide, incomplete isotopic homogenization of the magma, and a lack of uniform attainment of isotopic equilibrium during subsolidus cooling. The δ34S values of sulfide minerals have changed much less with cooling than have anhydrite values due in large part to the high sulfide/sulfate ratio. Variations in both sulfide and anhydrite δ34S values indicate that isotopically distinct domains existed on a centimeter scale. Late stage hydrothermal anhydrite and pyrite also occur associated with Ca-rich hydrous alteration assemblages (e.g., thomsonite, prehnite, pectolite, epidote, xonotlite). δ34S values of secondary hydrothermal anhydrite and pyrite determined by conventional analyses are in the same range as those of the magmatic minerals. Anhydrite-pyrite Δ values are in the 9.1-10.1‰ range, and are smaller than anticipated for the low temperatures indicated by the silicate alteration assemblages. The small Δ values are suggestive of either sulfate-sulfide isotopic disequilibrium or closure of the system to further exchange between ∼550 and 600 °C. Our results confirm the importance of the assimilation of externally derived sulfur in the generation of the elevated δ34S values in the Kharaelakh intrusion, but highlight the sulfur isotopic variability that may occur in magmatic systems. In addition, our results confirm the need for more precise experimental determination of sulfate-sulfide sulfur isotope fractionation factors in high-T systems.  相似文献   
93.
The Palaeoproterozoic Magondi Supergroup lies unconformably on the Archaean granitoid-greenstone terrain of the Zimbabwe Craton and experienced deformation and metamorphism at 2.06–1.96 Ga to form the Magondi Mobile Belt. The Magondi Supergroup comprises three lithostratigraphic units. Volcano-sedimentary rift deposits (Deweras Group) are unconformably overlain by passive margin, back-arc, and foreland basin sedimentary successions, including shallow-marine sedimentary rocks (Lomagundi Group) in the east, and deeper-water shelf to continental slope deposits in the west (Piriwiri Group). Based on the upward-coarsening trend and presence of volcanic rocks at the top of the Piriwiri and Lomagundi groups, the Piriwiri Group is considered to be a distal, deeper-water time-equivalent of the Lomagundi Group. The Magondi Supergroup experienced low-grade metamorphism in the southeastern zone, but the grade increases to upper greenschist and amphibolite facies grade to the north along strike and, more dramatically, across strike to the west, reaching upper amphibolite to granulite facies in the Piriwiri Group.  相似文献   
94.
Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al2O3–SiO2 and subsystem CaO–MgO–SiO2. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al2O3–SiO2 and subsystem CaO–MgO–SiO2. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 to $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 , D values for highly charged elements vary from $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 through $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 and $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 to $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 , and are all virtually independent of temperature. Cr and Co are the only compatible trace elements at the studied conditions. To elucidate charge-balancing mechanisms for incorporation of REE into Opx and to assess the possible influence of Fe on Opx-melt partitioning, we compare our experimental results with computer simulations. In these simulations, we examine major and minor trace element incorporation into the end-members enstatite (Mg2Si2O6) and ferrosilite (Fe2Si2O6). Calculated solution energies show that R2+ cations are more soluble in Opx than R3+ cations of similar size, consistent with experimental partitioning data. In addition, simulations show charge balancing of R3+ cations by coupled substitution with Li+ on the M1 site that is energetically favoured over coupled substitution involving Al–Si exchange on the tetrahedrally coordinated site. We derived best-fit values for ideal ionic radii r 0, maximum partition coefficients D 0, and apparent Young’s moduli E for substitutions onto the Opx M1 and M2 sites. Experimental r 0 values for R3+ substitutions are 0.66–0.67 ? for M1 and 0.82–0.87 ? for M2. Simulations for enstatite result in r 0 = 0.71–0.73 ? for M1 and ~0.79–0.87 ? for M2. Ferrosilite r 0 values are systematically larger by ~0.05 ? for both M1 and M2. The latter is opposite to experimental literature data, which appear to show a slight decrease in $ r_{0}^{{{\text{M}}2}} $ r_{0}^{{{\text{M}}2}} in the presence of Fe. Additional systematic studies in Fe-bearing systems are required to resolve this inconsistency and to develop predictive Opx-melt partitioning models for use in terrestrial and lunar magmatic differentiation models.  相似文献   
95.
The Huygens probe landed on the then unknown surface of Titan in January 2005. A small, protruding penetrometer, part of the Surface Science Package (SSP), was pushed into the surface material measuring the mechanical resistance of the ground as the probe impacted the landing site. We present laboratory penetrometry into room temperature surface analogue materials using a replica penetrometer to investigate further the nature of Titan’s surface and examine the sensor’s capabilities. The results are then compared to the flight instrument’s signature and suggest the Titan surface substrate material consists of sand-sized particles with a mean grain size ~2 mm. A possible thin 7 mm coating with mechanical properties similar to terrestrial snow may overlie this substrate, although due to the limited data we are unable to detect any further layering or grading within the near-surface material. The unusual weakening with depth of the signature returned from Titan has, to date, only been reproduced using a damp sand target that becomes progressively wetter with depth, and supports the suggestion that the surface may consist of a damp and cohesive material with interstitial liquid contained between its grains. Comparison with terrestrial analogues highlights the unusual nature of the landing site material.  相似文献   
96.
Understanding runoff generation processes is important for flood prediction, water management, erosion control, water quality, contaminant transport and the evaluation of impacts of land use change. However, little process research has been carried out in southern Chile. In particular the young volcanic ash soils, which are typical for this area, are not well understood in their hydrologic behaviour. To establish a ‘reference study’ which can then be used for comparison with other (disturbed) sites, this study focuses on the investigation of runoff generation processes in an undisturbed, forested catchment in the Chilean Andes. The paper reports on an investigation of these processes with different tracer methods at different spatial scales. Hydrograph separation with environmental isotopes and geochemical constituents was used on the catchment scale. Thermal energy was used as a tracer to investigate groundwater–surface water interactions at the local stream reach scale and dye tracers were used to study infiltration and percolation characteristics at the plot scale. It was found that pre‐event water dominates the storm hydrograph. In the lower reaches, however, water usually exfiltrates from the stream into the adjacent aquifer. The dye tracer experiments showed that while preferential vertical flow dominates under forest, water infiltrates as a straight horizontal front in the bare volcanic ashes (no vegetation) on the catchment rim. Subsurface flow patterns in the forest differ significantly from summer to winter. All three approaches used in this study suggest an important shift in dominant processes from dry to wet season. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
97.
98.
Quality of reprocessed GPS satellite orbits   总被引:4,自引:2,他引:2  
High-precision Global Positioning System (GPS) satellite orbits are one of the core products of the International GNSS Service (IGS). Since the establishment of the IGS in 1994, the quality and consistency of the IGS orbits has steadily been improved by advances in the modeling of GPS observations. However, due to these model improvements and reference frame changes, the time series of operational orbits are inhomogeneous and inconsistent. This problem can only be overcome by a complete reprocessing starting with the raw observation data. The quality of reprocessed GPS satellite orbits for the time period 1994–2005 will be assessed in this paper. Orbit fits show that the internal consistency of the orbits could be improved by a factor of about two in the early years. Comparisons with the operational IGS orbits show clear discontinuities whenever the reference frame was changed by the IGS. The independent validation with Satellite Laser Ranging (SLR) residuals shows an improvement of up to 30% whereas a systematic bias of 5 cm still persists.  相似文献   
99.
We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ11 B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ11 B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.  相似文献   
100.
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